catena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4N1,N1′:N3,N3′]dihydrate]
نویسندگان
چکیده
منابع مشابه
catena-Poly[[(2,2′-bipyrimidine-κ2 N 1,N 1′)diperchloratocopper(II)]-μ-4,4′-bipyridine-κ2 N:N′]
The central CuN(4)O(2) motif of the title compound, [Cu(ClO(4))(2)(C(8)H(6)N(4))(C(10)H(8)N(2))](n), exhibits a Jahn-Teller-distorted octa-hedral geometry around the metal centre, showing a considerably long Cu-O bond distance of 2.634 (4) Å towards the second perchlorate group occupying the sixth coordination site, giving a (4+1+1)-type coordination mode. The 4,4'-bipyridine (bipy) ligands are...
متن کاملcatena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4 N 1,N 1′:N 3,N 3′]dihydrate]
The asymmetric unit of the title compound, {[MnBr(2)(C(8)H(6)N(4))]·2H(2)O}(n), contains one half of a repeat unit of the neutral linear coordination polymer and a solvent water mol-ecule, with the Mn(II) ion on a crystallographic twofold axis. In the polymer, inversion-related Mn(II) ions are bridged by the bis-chelating 2,2'-bipyrimidine (bpym) ligands, thereby forming a chain structure along...
متن کاملμ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate
In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2'-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the inter-section of a twofold rotation axis and a m...
متن کاملcatena-Poly[trimethylphenylammonium [[bromidocadmate(II)]-μ-bromido-μ-chlorido]]
In the title salt, (C(9)H(14)N)[CdBr(2)Cl], the Cd(II) atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd(II) atoms, generating a linear polyanionic chain motif.
متن کاملcatena-Poly[heptylenediammonium [[tetrachloridobismuthate(III)]-μ-chlorido]]
The title organic-inorganic hybrid compound, {(C7H20N2)[BiCl5]} n , consists of distorted corner-joined [BiCl6] octa-hedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptyl-enedi-ammonium cations. The asymmetric unit contains two crystallographically independent bis-muth metal atoms, one of which lies on an inversion centre and the other on a twofold axis...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811049919